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Coordination chemistry

General data

Course ID: WM-CH-478
Erasmus code / ISCED: (unknown) / (unknown)
Course title: Coordination chemistry
Name in Polish: Chemia związków kompleksowych
Organizational unit: Faculty of Mathematics and Natural Sciences. School of Exact Sciences.
Course groups:
ECTS credit allocation (and other scores): 0 OR 4.00 OR 3.00 OR 2.00 (depends on study program) Basic information on ECTS credits allocation principles:
  • the annual hourly workload of the student’s work required to achieve the expected learning outcomes for a given stage is 1500-1800h, corresponding to 60 ECTS;
  • the student’s weekly hourly workload is 45 h;
  • 1 ECTS point corresponds to 25-30 hours of student work needed to achieve the assumed learning outcomes;
  • weekly student workload necessary to achieve the assumed learning outcomes allows to obtain 1.5 ECTS;
  • work required to pass the course, which has been assigned 3 ECTS, constitutes 10% of the semester student load.

view allocation of credits
Language: Polish
Subject level:

elementary

Learning outcome code/codes:

(in Polish) kierunek chemia 2 stopnia:CH2_W13; CH2_U01; CH2_U05; CH2_K07

Short description:

Electronic structure of complexes within the theory of crystal field and in the molecular orbital theory.

Magnetic and spectral properties of coordination complexes - basic description according to the theories as above.

Heat of complexation, the role of bonding.

Reactivity of coordination complexes: basic mechanisms of ligans substitution, redox processes.

Properties of the complexes illustrated by theIV-period transition series.

Comparison with organoimetallic compounds, basic definitions, similarities and differences.

Intermetallic bonds in complexes, clasters.

Coordination complexes as components of biological systems: capture and transport of oxygen, redox reactions, enzymes and catalytic cycles.

The role of complex compounds in Nature.

Full description:

chemistry of complexes

introduction, definitions, geometric structures, isomerism

crystal field theory

stability constants, chelate and macrocyclic effects, interpretations

formal oxidations states, electron count of central metal atoms (ions), examples

introduction of molecular orbital theory into description of electronic structure of complexes, examples of octa- and tetrahedral complexes

pi-complexes, description using the example of metal carbonyl complexes

reactivity of ligands in the complexed state, activation of CO and ligands containing this moiety

ligand substitution reactions, mechanisms, examples, reaction orders

redox reactions in coordination complexes, mechanisms, examples

introduction to organometallic chemistry, comparison to coordination complexes

intermetallic bonding, bond orders exceeding 3

functions of coordination complexes: redox processes, ion transport, catalysis

introduction to bioinorganic chemistry, the range of functionalities involving coordination complexes

oxygen capture and transport in living organisms, haemo/myoglobin system and blue proteins

redox processes, example of cytochrome 450, complexes in photosynthetic systems

supramolecular chemistry, coordination complexes in it

Bibliography: (in Polish)

D.F. Shriver, P.W. Atkins, C.H. Langford - "Inorganic chemistry", Oxford University Press, wyd. III, 1992, rozdziały 1.7, 4.15, 4.16 i 5.19 oraz wybrane fragmenty rozdziałów 4.14, 5.17 i 3.10

dodatkowa:

Efekty kształcenia i opis ECTS: (in Polish)

objaśnia barwę kompleksów koordynacyjnych

charakteryzuje budowę elektronową kompleksów koordynacyjnych

wylicza zastosowania kompleksów w procesach chemicznych

objaśnia rolę kompleksów w procesach zyciowych

rozpoznaje mechanizmy reaktywności kompleksów w procesach wymiany ligandów i w procesach redox

klasyfikuje wiązania w kompleksach

przewiduje właściwości prostych kompleksów

analizuje bionieorganiczne układy

zachowuje krytycyzm wobec niesprawdzonych informacji z zakresu chemii kompleksów i chemii bionieorganicznej

Assessment methods and assessment criteria: (in Polish)

samodzielna prezentacja

egzamin pisemny

Classes in period "Summer semester 2021/22" (past)

Time span: 2022-02-01 - 2022-06-30
Selected timetable range:
Navigate to timetable
Type of class:
Lectures, 30 hours more information
Coordinators: Janusz Lipkowski
Group instructors: Janusz Lipkowski
Students list: (inaccessible to you)
Examination: examination
(in Polish) E-Learning:

(in Polish) E-Learning (pełny kurs) z podziałem na grupy

Type of subject:

obligatory

(in Polish) Grupa przedmiotów ogólnouczenianych:

(in Polish) nie dotyczy

Course descriptions are protected by copyright.
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