Coordination chemistry
General data
Course ID: | WM-CH-478 |
Erasmus code / ISCED: | (unknown) / (unknown) |
Course title: | Coordination chemistry |
Name in Polish: | Chemia związków kompleksowych |
Organizational unit: | Faculty of Mathematics and Natural Sciences. School of Exact Sciences. |
Course groups: | |
ECTS credit allocation (and other scores): |
0 OR
4.00
OR
3.00
OR
2.00
(depends on study program)
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Language: | Polish |
Subject level: | elementary |
Learning outcome code/codes: | (in Polish) kierunek chemia 2 stopnia:CH2_W13; CH2_U01; CH2_U05; CH2_K07 |
Short description: |
Electronic structure of complexes within the theory of crystal field and in the molecular orbital theory. Magnetic and spectral properties of coordination complexes - basic description according to the theories as above. Heat of complexation, the role of bonding. Reactivity of coordination complexes: basic mechanisms of ligans substitution, redox processes. Properties of the complexes illustrated by theIV-period transition series. Comparison with organoimetallic compounds, basic definitions, similarities and differences. Intermetallic bonds in complexes, clasters. Coordination complexes as components of biological systems: capture and transport of oxygen, redox reactions, enzymes and catalytic cycles. The role of complex compounds in Nature. |
Full description: |
chemistry of complexes introduction, definitions, geometric structures, isomerism crystal field theory stability constants, chelate and macrocyclic effects, interpretations formal oxidations states, electron count of central metal atoms (ions), examples introduction of molecular orbital theory into description of electronic structure of complexes, examples of octa- and tetrahedral complexes pi-complexes, description using the example of metal carbonyl complexes reactivity of ligands in the complexed state, activation of CO and ligands containing this moiety ligand substitution reactions, mechanisms, examples, reaction orders redox reactions in coordination complexes, mechanisms, examples introduction to organometallic chemistry, comparison to coordination complexes intermetallic bonding, bond orders exceeding 3 functions of coordination complexes: redox processes, ion transport, catalysis introduction to bioinorganic chemistry, the range of functionalities involving coordination complexes oxygen capture and transport in living organisms, haemo/myoglobin system and blue proteins redox processes, example of cytochrome 450, complexes in photosynthetic systems supramolecular chemistry, coordination complexes in it |
Bibliography: |
(in Polish) D.F. Shriver, P.W. Atkins, C.H. Langford - "Inorganic chemistry", Oxford University Press, wyd. III, 1992, rozdziały 1.7, 4.15, 4.16 i 5.19 oraz wybrane fragmenty rozdziałów 4.14, 5.17 i 3.10 dodatkowa: |
Efekty kształcenia i opis ECTS: |
(in Polish) objaśnia barwę kompleksów koordynacyjnych charakteryzuje budowę elektronową kompleksów koordynacyjnych wylicza zastosowania kompleksów w procesach chemicznych objaśnia rolę kompleksów w procesach zyciowych rozpoznaje mechanizmy reaktywności kompleksów w procesach wymiany ligandów i w procesach redox klasyfikuje wiązania w kompleksach przewiduje właściwości prostych kompleksów analizuje bionieorganiczne układy zachowuje krytycyzm wobec niesprawdzonych informacji z zakresu chemii kompleksów i chemii bionieorganicznej |
Assessment methods and assessment criteria: |
(in Polish) samodzielna prezentacja egzamin pisemny |
Classes in period "Summer semester 2021/22" (past)
Time span: | 2022-02-01 - 2022-06-30 |
Navigate to timetable
MO TU WYK
W TH FR |
Type of class: |
Lectures, 30 hours
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Coordinators: | Janusz Lipkowski | |
Group instructors: | Janusz Lipkowski | |
Students list: | (inaccessible to you) | |
Examination: | examination | |
(in Polish) E-Learning: | (in Polish) E-Learning (pełny kurs) z podziałem na grupy |
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Type of subject: | obligatory |
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(in Polish) Grupa przedmiotów ogólnouczenianych: | (in Polish) nie dotyczy |
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